Electronic – alter this circuit

A solar panel is not a constant voltage, or constant current source. It can be thought of as a constant power source with maximum rated voltage and maximum rated current. The power is relative to the light hitting the panel, the voltage is maximum with no current, and drops as current is drawn from the panel.

If you are using a 10W panel, and it's in its full rated sun exposure, you'll get 10W out.

If you draw 1A in that situation, the voltage will be about 10V. If you draw two amps, the voltage will be about 5V.

If your battery is full, you probably aren't going to draw much current, so the voltage is higher.

If the battery is nearly empty, it will draw a lot of current, and it will cause the panel's voltage to drop.

In your specific case, what you're finding is that the panel can't provide full charging current all the time - whether that's due to less than full sun exposure, or a low-charge battery depends on the situation.

However, you can still use this system, even though the voltage is low. If you disconnect the battery and measure its voltage, then connect it to the charging system and measure the voltage at the battery, you'll find that the attached voltage is higher - the battery is accepting current from the system, and is charging. It isn't charging as fast as it could be, but that's due to the panel's limitations.

If you want to learn more about this, and what professional solar charging systems do in order to handle this effect, do a search for MPPT circuits - maximum power point tracking. The solar panel is most efficient at a certain voltage and current for a given sunlight input, and these circuits attempt to track that maximum point so you get as much power from the panel as possible.

Also, note that SLA batteries are very forgiving. It may be that you can eliminate the voltage regulator, and just use the diode in the circuit. This will increase the voltage at the battery since the regulator drops 1.5V-3V depending on load, and thus charging efficiency. Given that you're having a hard time keeping it charged, I'd expect the solar panel is unlikely to damage the battery, but check the panel's maximum current at 7.2V and see if the battery can accept a constant trickle charge of that rate.

I think that a very good option is to take advantage of the PIC uC that you already have in your design and its analog (ADC) input ports for monitoring the batteries voltage and to drive the switching between those batteries using MOSFETs instead of BJT transistors. Using the uC you should not need the two comparators that you show in the picture and you will have a more intelligent charging/monitoring battery circuit that could lead to improve the batteries duration. This uC could stay in sleep mode (or low power mode as second option) all the time using interrupts to read the ADC channels. You should run the uC from its internal RC oscillator operating at the lowest frequency as possible to decrease the power consumption.

I also recommend you using Schottky diodes instead of 1N4148 and to put a small bulk capacitor at the output of the power selector circuit (or switching circuit). Those Schottky diodes will drop less voltage than the 4148.

If you decide to use the uC for the battery voltage level monitoring, try to use the internal fixed voltage thresholds that the uC provides for the internal comparators, because if you don't do that you could have some problems reading wrong analog values because those batteries are used to power the uC too (you will have ratiometric voltages).

I hope this help.