Interesting question because I can see the answer going either way, depending on environmental circumstances.
Some aspects of the design which may not be immediately obvious...
1) Switchers are notoriously poor at a tiny fraction of their load - they may consume several mA internally, or they may lose regulation and deliver 7V below some value, say 1% of rated load (10mA in your case) without special care in design.
2) One answer could be a linear regulator during sleep, (even from 11V but there's nothing wrong with a 2S Li-Ion - nominally 7.4V max 8.4V) and the MPU has to wake up a switcher before transmitting. If the linear regulator only supplies a few mA, you can probably find a SOT-23 to do the job, or SOIC-8 at the largest, so I don't believe size is the issue
3) A linear regulator for 1A will need some heatsinking even for 20 seconds ... if there's a convenient chunk of metal, use it. Linear may be more reliable from its simplicity. But what happens if the TX gets stuck "on"? Running the battery flat is one thing, destroying the equipment is another... .
4) I would not, personally, change battery technology simply as a way of tuning supply voltages. If you need lower fire hazard, or greater charge/discharge cycles, or some characteristic of LiFePO4 that's a reason for using them - otherwise stick with commodity batteries for economics and simpler servicing.
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Yes, you could add an entire extra linear voltage regulator and capacitors for a voltage rail you don't even need, just to spread out power dissipation.
Or you could just use a resistor.
You say your problem is reliability? Then let me tell you about the most reliable electrical component ever made: the resistor. They're the only component that can, albeit unreliably, continue to function even after catching fire. Heck, I've seen those beefy sandstone power resistors explode a little and still work, at least until they explode a lot.
But I digress.
Just put some resistors between the 12V buck-boost converter and your 7805. You can parallel several if you like to really spread out the dissipation and give yourself lots of head room. This will be the most reliable, simple, and inexpensive solution.
And, as a bonus, you will almost certainly get better ripple reduction than cascading an additional 780x (7809 in your case).
The 780x series regulators are fairly slow. They have ~60-70dBV of ripple rejection but only if that ripple is 120Hz. I don't know what frequency your dc/dc converter is operating at, but it is almost certainly 100kHz or more, and will have switching harmonics into the MHz. Those will shoot through a slow linear regulator like the 7809 like a bullet shoots through air.
Ok, it's not quite that bad, but I would be surprised if you got more than 40dBV of rejection at 100kHz, and if your buck-boost converter is faster, it could be 20dBV or even worse.
But do you know what you get if you have a resistor in series with a capacitor? A low pass filter! YAY! And if you placed a voltage dropping resistor before your LM7805, you very conveniently have just such a capacitor - the input capacitor for the linear regulator. Sure, the 7805 needs a nice low impedance input, but that's what the capacitor is for. And since you know your maximum load current, you its a trivial matter to size your voltage dropping resistor. Its really just a matter of how much heat you want to dissipate in the resistor(s) vs. in the linear regulator. The nice thing about, say, 1W resistors, is that they don't mind getting hot and will dump that heat with natural convection alone, so I would recommend favoring the resistors when it comes to shedding watts.
I'll just do a quick and dirty example. At 500mA load current, let's drop the voltage to exactly what you'd get with a 7809. To do that, we need a 6Ω resistor. If you want to be really safe, perhaps use 3 18Ω 1W resistors in parallel, then each one will only have to dissipate 500mW. They will drop the voltage to 9V before it even reaches the 7805. If you put a nice fat ceramic directly on the input of the 7805, perhaps a 47µF one or even a fancy 100µF one, in all its 0805 sized glory, you'll solve your problem in a very reliable way, AND have a beefy low pass filter that will give you better ripple rejection than an extra linear regulator ever could, especially at higher frequencies.
And if you really want to clean up the voltage even more, toss in a ferrite bead in series between the resistors and the input capacitor. Ferrite beads are wonderful little critters. Unlike inductors, which might reduce ripple but also radiate some of that energy out as EMI and almost certainly make the situation worse, ferrite beads take high frequency ripple and dissipate it as heat due to core losses. They're best thought of as frequency dependent resistors that only have resistance above certain frequencies. They will aid you a great deal when it comes to cleaning up the analog sections of circuits - now is the best time to start using them!
If you still really have your heart set on adding a 7809, then you can still solve your problem this way. Add a smaller series resistor between the 7809's output and the 7805's input. This will dissipate a bit of power and spread things out further, and will decouple the 7809's output capacitor from the 7805's input capacitor. Just use the values you would if the regulators were being used by themselves. The input capacitor is what provides the low impedance power to the voltage regulator, so it is perfectly fine to have some resistance in series with the input, as long as it is before the input capacitor. Never put it between the input capacitor and the regulators actual input, obviously.
Best Answer
Linear regulators work by effectively putting a controlled variable resistor between the source and load. All of the current for the load flows through this resistive element. And the voltage across it is equal to the difference between source voltage and load voltage. So the power dissipated is
\$P_{lin} = I_{load}\times{}(V_{src}-V_{load})\$.
Switching regulators work by changing the duty cycle of the current flow over a switching cycle, then averaging out the output using a filter. During part of the cycle a high current flows with a low voltage drop. During the other part of the cycle almost no current flows with a high voltage drop. Neither of these conditions dissipates much power as heat. Ideally the power lost becomes
\$P_{sw}= \mathrm{DC}(I_{on})(0\ \mathrm{V}) + (1-\mathrm{DC})(0\ \mathrm{A})(V_{off})\$,
which is, of course, 0 W. Typically much of the inefficiency in the real world is due to power lost during the very short switching inteval between the "on" and "off" parts of the cycle.