It is a long question, but better than a short one, as you've shown your own research.
1) Solar cells. If you're stacking your own ones, stack 9 of them and get the 4.5V of the original circuit.
2) Battery charging. Batteries are the only thing you've left out of your spec. This is an area where the circuit design relies on cutting a lot of corners. In theory it might be out of spec, if you were to put 4.5V at 280ma through AA NiMH cells indefinitely. In practice, you don't get full sun all day, you'll be using it indoors, and you're not going to get optimal power transfer from the cells, so this isn't going to cause problems.
3) Diode. It's just a regular diode, not a zener. Current through it is actually determined by the battery and right hand side circuit, not the solar panel - the transistor is off when the panel is generating electricity. The original 1N914 will be fine. 1N4004 will also be fine.
4) Resistors: not a precision component here, use whatever meets your cost constraint. 5.1k for 5k is fine.
5) Wire: not critical. Your ebay link looks suitable. Thinner is better for the toroid.
6) Transistors: stick with the exact part numbers. Design may rely on specific parameters.
7) LED: again, this circuit relies on cheating. Normally a white LED won't run from two NiMH cells. The joule thief part provides a boost converter that gives small pulses of higher voltage. It doesn't have the capacity to provide a lot of current at that voltage. In combination with the pulsing this means there should be no risk of damaging it.
(A proper analysis of this circuit would be good, if nobody else supplies one I'll do it in a few days).
Yes. The current through the converter is determined by the load. I doubt the monitor is pulling all 5 amps from the original supply anyway. Just throw an ammeter on the ground of the pc side and measure it to be in the safe side, but it should work without modification. With 100% efficiency the input would be, at max draw, 12v 10A, for 24v 5A. In free air inside the pc case, with fans you should be alright assuming 4A load draw
Best Answer
No need to overcomplicate things.
Texas TPS61096A will solve all your issues.
TI
Linear LTC3119 with MPPC (fixed point MPPT) would be even better due to your solar input.
Linear