Your design is good. It is OK to use 50 Hz isolating transformer and then buck DC-DC stage. However: you should take care of interference and isolation. This may be not so easy, if you do not have good enough PCB technology at hand.
You can not make your buck stage on one IC because of high voltage / power requirements. You can use ready-made buck controller (for example, LTC3810) and two small power MOSFETs rated for 80 V operation. LTC3810 can regulate its output in range from 0.8 V to 50 V. You have to select the proper feedback correction to run the switching regulator in such a huge output voltage range.
Additional benefits of this design are: built-in over-current protection and soft start.
The problem is: you need a good PCB technology to make this design work fine.
As for the switching noise - it is only a matter of proper filtering. I have designed a lot of very sensitive analog and RF circuits, all containing switching regulators. It is enough to filter the output by one or two stage LC filter with MLC capacitors and low quality factor inductors. I suggest to add one common mode choke on output of your DC-DC stage and another one - on its input.
The linear regulator after the switching one does not help against a switching noise, it is a myth. You can check specs for linear regulators for AC suppression: it is pretty low above 0.5 MHz. And we are talking about noise / interference from the switching frequency up to 100 MHz, at least. So cheap passive components (inductors, ferrite beads and MLCC) solve this problem.
The only drawback of using 50 Hz transformer compared to fly-back switching design is: the capacitance between Mains and your DC output is ~100 times larger with 50 Hz transformer. It may cause problems in RF applications.
Once again: your major problem in this design is the PCB technology (2 layers is absolute minimum, 4 is good) and proper PCB layout design.
My standard way to initially estimate the total VA rating of a transformer is to weigh it, and then compare the weight with published figures from a transformer catalogue. From for instance, RS conventional EI transformers weighing 500g are rated at 20VA, whereas toroidal transformers of the same weight are rated 30VA.
This is the total VA, what you would expect the primary to handle. You have to divide this amongst the secondaries.
You have the measured voltage \$V\$ and the measured resistance \$R\$ of the windings.
There are two limitations to the max current that can be drawn from secondaries, regulation (voltage drop) and temperature rise.
Regulation is easy to handle, as it can easily be estimated from the current we want to draw \$I\$ as \$V_{drop} = IR\$. This doesn't damage the transformer, only affects our load, and whether the voltage is sufficient at the load.
Temperature rise is more difficult, and can damage the transformer. We can see how warm the transformer gets to the touch, but that doesn't tell us whether one particular winding is getting too hot or not.
If we assume that all windings are cooled to ambient in the same way (which is not too wrong, especially for a first stab, and especially for a toroidal) then the VA of a winding is proportional to the mass \$m\$ of copper used in it, regardless of the number of turns \$N\$, length \$L\$ or wire area \$A\$.
As \$V\propto N \propto L\$, and \$R\propto \frac{L}{A}\$, we can see that the mass varies as \$m \propto \frac{V^2}{R}\$
I'll leave it as an exercise for you to prove this, hint, dimensional analysis helps (don't forget the dimensions of the constants of proportionality). Note that the expression itself has units of power, which we would expect as it's supposed to help estimate VA.
So, for each secondary, calculate \$V^2/R\$, and apportion your total 20 or 30VA in proportion, this is your estimate of VA for each winding.
Having got initial estimates for the VA of individual windings, fire the transformer up from a fused supply. Load each winding with a resistor to draw half your calculated VA, and measure the voltage drop. Make sure this is reasonable (a few percent for big transformers, possibly 10% for small ones) for all windings before you continue the test.
Load all windings with half your calculated VA, and let it run for 30 mins to reach thermal equilibrium. Now disconnect everything, and quickly measure the resistance of each winding before they have had a chance to change temperature. You can estimate the temperature rise of each winding by knowing that copper has a tempco of 0.4% per degree C at room temperature. For example, if your 2.5ohm winding went to 2.75ohm (+10%), that indicates a 25C rise above ambient. You may need to do a four-terminal measurement to get differences accurate enough to be worth using at the ohm level.
If any winding is particularly hot or cool, you can vary the proportional of the total VA going to it, and try again. The maximum temperature a winding can reach is governed by the insulation used on the transformer. I don't like to go above 70C (remember if you box the transformer up, its ambient will increase) without knowing more about the specific wire used.
Before you finally test the transformer at full VA, remember the temperature rise of the transformer is proportional to \$I^2\$, so the half VA temperature rise you measured was one quarter of the final, not half!
Best Answer
Windings 1-3 and 2-4 are the same. The rest are "12V" windings.
If you connect the 1-3 and 2-4 in series the turns ratio will change from 2.5:1 to 5:1 and the output voltage will go down by half.
You should be able to put the secondary winding in parallel or in series depending on what you want.