What’s the proper soldering iron temperature for standard .031" 60/40 solder?
There is no proper soldering iron temperature just for a given type of solder - the iron temperature should be set for both the component and the solder.
When soldering surface mount components, a small tip and 600F (315C) should be sufficient to quickly solder the joint well without overheating the component.
When soldering through hole components, 700F (370C) is useful to pump more heat into the wire and plated hole to solder it quickly.
A negative capacitor lead to a heatsinking solid pour ground plane is going to need a big fat tip at a much higher temperature.
However, I don't micromanage my soldering temperature, and simply keep mine at 700F (370C). I'll change the tips according to what I'm soldering, and the tip size really ends up determining how much heat gets into the joint in a given period of contact.
I think you'll find that very few soldering jobs will really require you to change your tip temperature.
Keep in mind that the ideal situation is that the soldering iron heats up the joint enough that the joint melts the solder - not the iron. So the iron is expected to be hotter than the melting point of the solder so that the entire joint comes up to the melting point of the solder quickly.
The more quickly you bring the joint temperature up and solder it, the less time the soldering iron is on the joint, and thus the less heat gets transferred to the component. It's not a big deal for many passive or small components, but it turns out that overall a higher tip temperature results in faster soldering and less likely damage to the component being soldered.
So if you do use higher tip temperatures, don't leave them on components any longer than necessary. Apply the iron, apply the solder, and remove both - it should take just a second or maybe two for surface mount, and 1-3 seconds for a through hole part.
Please note that I'm talking about prototyping, hobbyist, and one-off projects. If you are planning on doing final assembly with the iron, repair work for critical projects, etc, then you'll need to consider what you're doing more carefully than this general rule of thumb.
(Solid) tip "tinners" are almost always ammonium phosphate with some tin (or tin-lead) bits mixed in. They are moderately aggressive at cleaning oxides off, so shouldn't be used constantly, but only when needed. The best tip tinner is your solder--tips should always be coated with a small amount of solder.
If some of the oxides are just sticking really well, you could try to mildly abrade them on a brass sponge, copper braid, or similar, but you can't be too hard or you will damage the iron plating (good tips are typically copper core, plated with iron, then chromium everywhere but the working area).
Practice good tip care. I use a Hakko iron and tips at work and mine has lasted about a year (moderately light use, maybe 5-6 projects). Put a good amount of solder on the tip when storing it or leaving it idle for any length of time; don't, for instance, wipe it off, put it in the holder, then leave it on over lunch.
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Best Answer
I would say that 2mm is probably a little on the large side but a lot if it is down to personal opinion.
However there are some important things to consider when choosing the tip size.
I generally find the standard tip most irons come with okay for pretty much anything.