Electronic – Does electric current prevent corrosion or oxidation

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I often see overhead power lines without any shielding from the elements. Are these lines galvanized or does current protect them from corrosion? Wouldn't the electron flow through the metal wires prevent oxygen from bonding to it? At the same time, however, you could claim it would have no effect. The corrosive elements, air, water, etc, do not have the same voltage reference.

Finally, can carefully limited electric current be used as an anti-corrosion method?

Best Answer

Current thru a metal has no effect on corrosion. However, corrosion is a electro-chemical process, so current into or out of a conductor does effect its chemical activity over surface the current flows into or out of.

This is exactly the effect galvanizing exploits to reduce corrosion of ferrous metals. The zinc coating does directly protect the metal underneath.

However, the special properties of galvanizing kick in when there is a hole in the zinc protective layer. Now you have zinc and iron exposed to the same electrolyte. A current will flow due to this battery. The direction of the current is such to reduce corrosion of the iron, while instead corroding the zinc.

In some cases, like off shore oil platforms for example, it is cheaper and more effective to put zinc anodes in various places than to coat the steel with zinc. One advantage is that the zinc electrodes can be periodically replaced as they get corroded away. In fact they are often referred to as sacrificial anodes. Divers going down and replacing the zinc blocks is part of routine maintenance.

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