Electronic – How to estimate Li Ion Battery SOC

batteriesbattery-chargingefficiencylithium ion

In a simple model of a renewable energy system, I have a residential inverer and Lithium ion battery system with a round-trip efficiency (for inverter and battery, i.e. ac to ac) of 89% (at 25 degrees and a given charge / discharge power). The model needs to calculate the SOC of the battery (to determine when it's fully charged, etc.) which requires me to distinguish between charging and discharging efficiencies. Some studies assume the inefficiency is in charging, so SOC = 89% of charging energy, but this seems unlikely. Is it reasonable to assume that the losses for charging and discharging are approximately equal, so the charge and discharge efficiencies would both be approximately 94.3% (square root of 89%) or is there some other rule of thumb?

To clarify: this is a techno-economic model and is only concerned with energy flows in the system.
If n(charge) is the charging efficiency and n(discharge) the discharge efficiency, all I know (from the manufacturer) is n(cycle) = n(charge) * n(discharge) = 0.89

For example, in time period t1, energy delta(E) is sent to the battery-inverter system and – if the battery has unused capacity – increases the energy stored in the battery by delta(E) * n(charge). The change in the state of charge is then:

delta(SOC) = delta(E) * n(charge) / usable capacity

I need to estimate SOC to know whether the battery has capacity to take delta(E).

Best Answer

It is not entirely clear what you are getting at. What you SHOULD do if your model is detailed enough is periodically measure battery current and sum during charge and discharge to keep track of Amp-hours. Charge amp-hours and discharge amp-hours are very close to equal (very high Coulombic efficiency). The energy loss due to charge and discharge is mostly due to voltage differences. The voltage during discharge is lower than the voltage during charge, so even though the cumulative charge is the same, the energy is not.

The figures you are quoting may involve DC-DC converter losses or inverter losses. It is hard to tell from your question. But if the round-trip efficiency for the battery itself is 89%, that is probably due entirely to voltage difference. I don't really see how it can be apportioned between charge and discharge, nor do I see why it would be necessary to apportion it that way. Maybe it would be more clear if you provided more detail about your model. Maybe your battery model could just use an ideal battery with a small resistor in series.