Electronic – Nature of conventional current flow in a p-n junction

pn-junction

More specifically, I'm confused about the concept of hole diffusion. I can understand that electrons diffuse towards the p-type material. However, the concept of holes diffusing is a little bit strange.

When I think about the diffusion current that occurs in the depletion region, I imagine moving the electron from a donor atom in the n-type material, leaving behind a positively charged ion, to an acceptor atom, filling the hole associated with it and creating a negatively charged ion. The result is that the total charges in the diode are conserved, but a conduction electron and hole are annihilated. Wouldn't it be more accurate to say that the electrons "fill" the holes in the p-type material?

I suppose another way to ask this question is the following. Would it be accurate to say that positive current in a p-n junction involves hole movement in the p-side, but when it comes to the n-side, involves "movement" of positive charge by positive ions? I'm not sure that the absence of the extra electron at a donor atom is considered to be a "hole", but it seems like from this level of analysis it could be viewed as one.

Best Answer

but when it comes to the n-side, involves "movement" of positive charge by positive ions?

Nope, for the most part, the positive ions in the n-side are the pos-charged dopant atoms, and those are locked into the crystal lattice.

It's confusing because there are actually four ions involved, not just two.

First, in the p-doped silicon, the neutral dopant atoms don't remain neutral. Instead, a "hole" is created by each dopant atom, and it moves away. This leaves the dopant atom with net negative charge. Yet the wandering "hole" is actually a positively-ionized silicon atom! At the same time, on average the entire hunk of p-type silicon has zero net-charge. After all, every positive-charged hole has a negative-charged dopant ion somewhere nearby. In other words, p-type silicon is actually made up of equal quantities of:

  1. fixed negative-charged dopant ions
  2. movable positive-charged silicon ions (the wandering "holes.")

The n-type silicon is the opposite. The dopant atoms in n-type silicon will contribute wandering electrons. But when each electron initially leaves its dopant atom, that atom becomes a positive-charged ion. And, when the wandering electron is sitting upon some distant silicon atom, that atom temporarily becomes a negative silicon ion. So, n-type silicon is overall neutral, but is is composed of:

  1. fixed positive-charged dopant ions
  2. movable negative charged silicon ions (the mobile electrons.)

It gets worse!

Suppose that some holes wandered out of the p-side and invaded the n-type silicon? Thermal motion causes them to jump around randomly, and the random jumping can take them over into the n-side. They won't last long over there, but while they're briefly existing in the n-side, the holes are producing a region of positive net-charge! (After all, they no longer are near their negative-charged dopant atoms, which were all left behind in the p-type side.)

but when it comes to the n-side, involves "movement" of positive charge by positive ions?

YES! Because actually a "hole" is a positive-charged silicon ion ...so if holes invade the n-side, electrically it's just as if some pos-charged silicon atoms were invading. Yet the atoms themselves don't have to move. Just their "ionization" is wandering around through the crystal. (Heh, but at the same time, the n-side is full of positive-charged dopant ions which cannot move. So, whenever n-type silicon is full of wandering holes, it actually contains two kinds of positive ions, but only one of them can move around.)

PS

Important question: does p-type silicon have a positive charge? Nope, since p-type silicon is full of non-movable negative dopant ions. Their quantity is exactly the same as the quantity of wandering, positive-charged holes. P-type silicon is a conductor of course, and that means we can give it a positive net-charge by hooking it to the positive terminal of a power supply.

And to make things even more interesting, if we connect p-type to n-type, some electrons will diffuse from n-type to p-type and become trapped in the depletion zone (because they encountered holes, and "fell in.") This causes the p-type side to become negative charged, and the n-type side to become equally positive. This is the "built-in potential" of semiconductor junctions, which is caused by the "built-in" trapping of mobile charges in the depletion-zone. Or in other words, a diode junction is also a spontaneously self-charged capacitor.