Electronic – Recharging NiMH cells after long period (18 months) of self discharge

battery-chargingnimh

I have seen information supplied with branded NiMH cells (e.g. Duracell) saying "do not leave cells for more than 6 months without recharging."

I have some AA size cells which were fully charged around 18 months to 2 years ago, but have since been left unused. During that time they have not been installed in any battery powered devices, and kept at normal household temperature and humidity levels. They have no visible damage.

Attempting to recharge them with my usual charger doesn't work – I assume their voltage is so low that the charger protection circuit is cutting in to protect the charger. If it's relevant, the charger is designed to fully charge either 2 or 4 cells, either AA or AAA size, in about 2 hours.

Is there any relatively simple (and safe!) way to recharge them to the point where a commercial charger will at least try to recharge them fully?

It wouldn't cost a huge amount of money just to replace them with new ones, but my natural inclination is "don't scrap stuff unless you really have to!"

Best Answer

I do not expect these cells to be damaged. Contrary to Lithium based cells, which are indeed damaged when fully discharged, NiMh cells can handle this as long as they are not reverse charged.

Reverse charging can happen when the cells are used in for example a camera and one of the cells has less capacity. When it is empty it will be reverse charged while the other cells still provide current.

But you appear to have left the cells on their own so reverse charging cannot happen in this case. The cells just emptied themselves due to self-discharge.

Personally I would use my lab supply to "kick the cells into life" with 0.5 A of current for 10 seconds or so while measuring their voltage.

If you do not have a lab supply but you do have a "dumb" charger (one where it takes 10 hours or so to a full charge) you could try to charge the cells in that. Since such a charger does not check the cell's voltage but simply charges with a small current, the cells might become alive again after an hour.