This touches on basically two things: AC current and electrical machines. Let's start with the first.
The war of the currents was very, very long ago. In a time where there was only theoretical understanding of switching power supplies, but no means to actually implement this kind of device. In order to distribute power over long distances, you want to reduce the current as much as possible because current is what causes losses. So you want to have very high voltages, in the 400kV-4MV range. However, as you distribute out towards smaller and smaller units, the required physical size of such conductors as well as safety issues require the use of lower voltages. In homes, you want to use safe low voltages, i.e. <600V. For medium scale distribution, something in between is preferred, nowadays standardized to 10-40kV. So for grid-scale distribution, you require at least two big conversion steps.
By far the easiest and most reliable way to do this is with transformers. They are solid-state, very well understood, absolute lowest complexity. Of course, transformers only work well with AC current of some kind, and in order to minimize overall transformer size but avoid the worst parts of skin and proximity effects, we chose about 50-60Hz as the AC frequency. This is why things are the way they are now.
However, this does not mean that AC is 'better' than DC. At the time, using AC was the better choice. Nowadays, DC is. At least for grid purposes.
AC is a much less efficient way of transporting large amounts of power. It is required for transformers, but otherwise it is horrible. It is very easy to do a first-order calculation to see how bad this is.
Take a distribution system that has a 1000V conductor insulation rating, i.e. I can safely transport energy at 1000V. Let's say I want to transport 1000W of power over here. This means that I can either do 1000V, 1A or 707VAC, 1.4A. It is immediately clear that DC resistance losses in this transmission line will be \$I^2=(\sqrt{2})^2=2\$ times as high for AC compared to DC. Or alternatively, a transmission line with equal current rating will be able to carry \$\sqrt{2}\$ times the power when operated with DC instead of AC.
However, there are more distribution advantages to DC. The most prominent is skin effect, although the proximity effect is something you might also want to look up. Skin effect causes changing current to bunch up near the surface ('skin') of a conductor. This means that the current density is not uniform over the conductor cross-section, and this causes the effective resistance of the wire to increase as frequency goes up. Especially when dealing with very high currents like in transmission lines, this can cause tens or hundreds of percents of effective resistance increase. A mitigation is to use hollow wires, wound plate or Litz wire, but these are fairly expensive methods.
Now, with DC transmission being very clearly the best solution of power transmission, why don't we do that everywhere? The reason is simply of cost and complexity. Even though we have very efficient and reliable DC-to-DC grid converters nowadays, they are inherently much more complex and still measurably less reliable than old fashioned transformers. Until very recently (post-2000!) the increased cost of maintenance and increase in downtime weren't worth the 40+% reduction in effective grid losses.
So that is why ideally, you want to use DC everywhere where otherwise AC would be used. Now onto the machine discussion.
This also boils down to an efficiency/performance vs. cost discussion. Very analogously to the transmission line argument, DC motors have performance that is very favourable for use in transportation equipment. AC motors generally sport piss-poor stall torque, whereas torque at stall is maximum for DC motors. Also, power density is much better with DC motors, reducing physical size, weight, etc. All very nice things for transportation. Also, it is very easy to do regenerative braking on DC motors, whereas AC motors require some more work in order to regenerate into a battery.
The downside is obvious: they need brushes, and those require maintenance. AC induction motors are basically safe life, so they don't ever need maintenance. Even though they are technically inferior in most ways, lately they have been increasingly employed in public transportation. The biggest downsides of yore - very pronounced cogging despite using skewed squirrel cages, lack of torque, complexity of frequency drives (yes, most public transportation runs from DC transmission lines, so you need to do conversion to AC with a machine drive of sorts) have basically been sorted out. Also, AC induction motors scale better with higher power - a 1MW induction motor is actually smaller than a DC brushed variant. And apparently - I don't have the exact stats but this is what I have been told - the slightly lower efficiency and drive concerns are easily offset by lower maintenance.
The problem is that the rotor and stator must have spaces called slots, in the iron for the conductors. The conductors and air in the slots have a lower reluctance than the reluctance of the iron. There are more slots than there are poles in the stator. The windings are distributed among the slots to form distributed poles. Their is a different numbers of slots used for the stator and rotor. Those two features prevent the rotor from becoming locked or "cogged" in the minimum reluctance position that would otherwise exist.
Even with proper selection of the number of stator and rotor slots, there can be reluctance variations at different rotor angles that cause torque fluctuations and inflections in the torque vs. speed curve. Skewing the rotor slots mitigates that effect.
Here is a picture of the rotor and stator of a 4-pole, permanent-split capacitor, single-phase induction motor.
Best Answer
It will work, but not as well.
A copper shell would not have the permeability to get a good field through it. An iron shell would not have the conductivity to allow high currents with low loss. In either case, the motor would have to be significantly bigger than they are now for the same power, and would be less efficient.
If we could use unobtanium metal, with this combination of good magnetic and electrical properties, then we could use a single metal shell. We can't get unobtanium, so this combination of iron and copper is the best we can do from what nature provides.
A single metal shell would be cheaper to make than the present bi-metal construction. We can therefore assume that it's worth spending the extra money to fabricate the squirrel cage, that the extra performance and size reduction is worth the extra cost to make.