Lvm – RAID6 mdraid -> LVM -> EXT4 root with GRUB2

You need to install GRUB to the MBR of both drives, and you need to do it in a way that GRUB considers each disk to be the first disk in the system.

GRUB uses its own enumeration for disks, which is abstracted from what the Linux kernel presents. You can change which device it thinks is the first disk (hd0), by using a "device" line in the grub shell, like so:

device (hd0) /dev/sdb

This tells grub that, for all subsequent commands, treat /dev/sdb as the disk hd0. From here you can complete the installation manually:

device (hd0) /dev/sdb
root (hd0,0)
setup (hd0)

This sets up GRUB on the first partition of the disk it considers to be hd0, which you've just set as /dev/sdb.

I do the same for both /dev/sda and /dev/sdb, just to be sure.

Edited to add: I always found the Gentoo Wiki handy, until I did this often enough to commit it to memory.

Every time you perform an operation with LVM, by default, the previous metadata is archived in /etc/lvm/archive. You can use vgcfgrestore to restore it, or grab the extends by hand (harder, but lvcreate(8) should cover it).

Edit:

And to make it as easy as possible, I should add that you can find the last backup before your destructive operation by looking at descriptions:

# grep description /etc/lvm/archive/vg01_*
/etc/lvm/archive/vg01_00001.vg:description = "Created before executing 'lvremove -f /dev/vg01/foo'"
/etc/lvm/archive/vg01_00002.vg:description = "Created before executing 'lvremove -f /dev/vg01/bar'"
/etc/lvm/archive/vg01_00003.vg:description = "Created before executing 'lvremove -f /dev/vg01/baz'"

Edit:

The normal allocation policy (default one) will allocate a stripe from the first free PE when there is enough room to do so. If you want to confirm where the LV was allocated, you can look in the archive files, those are perfectly readable by humans.