C# – The default for KeyValuePair

string is an alias in C# for System.String.
So technically, there is no difference. It's like int vs. System.Int32.

As far as guidelines, it's generally recommended to use string any time you're referring to an object.

e.g.

string place = "world";

Likewise, I think it's generally recommended to use String if you need to refer specifically to the class.

e.g.

string greet = String.Format("Hello {0}!", place);

This is the style that Microsoft tends to use in their examples.

It appears that the guidance in this area may have changed, as StyleCop now enforces the use of the C# specific aliases.

I still think var can make code more readable in some cases. If I have a Customer class with an Orders property, and I want to assign that to a variable, I will just do this:

var orders = cust.Orders;

I don't care if Customer.Orders is IEnumerable<Order>, ObservableCollection<Order> or BindingList<Order> - all I want is to keep that list in memory to iterate over it or get its count or something later on.

Contrast the above declaration with:

ObservableCollection<Order> orders = cust.Orders;

To me, the type name is just noise. And if I go back and decide to change the type of the Customer.Orders down the track (say from ObservableCollection<Order> to IList<Order>) then I need to change that declaration too - something I wouldn't have to do if I'd used var in the first place.