C++ – the simplest way to convert char[] to/from tchar[] in C/C++(ms)

string is an alias in C# for System.String.
So technically, there is no difference. It's like int vs. System.Int32.

As far as guidelines, it's generally recommended to use string any time you're referring to an object.

e.g.

string place = "world";

Likewise, I think it's generally recommended to use String if you need to refer specifically to the class.

e.g.

string greet = String.Format("Hello {0}!", place);

This is the style that Microsoft tends to use in their examples.

It appears that the guidance in this area may have changed, as StyleCop now enforces the use of the C# specific aliases.

In practice, the difference is in the location where the preprocessor searches for the included file.

For #include <filename> the preprocessor searches in an implementation dependent manner, normally in search directories pre-designated by the compiler/IDE. This method is normally used to include standard library header files.

For #include "filename" the preprocessor searches first in the same directory as the file containing the directive, and then follows the search path used for the #include <filename> form. This method is normally used to include programmer-defined header files.

A more complete description is available in the GCC documentation on search paths.