.net – File.Move not working properly for UNC paths

The way to solve your problem is to use a Win32 API called WNetUseConnection.
Use this function to connect to a UNC path with authentication, NOT to map a drive.

This will allow you to connect to a remote machine, even if it is not on the same domain, and even if it has a different username and password.

Once you have used WNetUseConnection you will be able to access the file via a UNC path as if you were on the same domain. The best way is probably through the administrative built in shares.
Example: \\computername\c$\program files\Folder\file.txt

Here is some sample C# code that uses WNetUseConnection.
Note, for the NetResource, you should pass null for the lpLocalName and lpProvider. The dwType should be RESOURCETYPE_DISK. The lpRemoteName should be \\ComputerName.

using System;
using System.Runtime.InteropServices ;
using System.Threading;

namespace ExtremeMirror
{
    public class PinvokeWindowsNetworking
    {
        #region Consts
        const int RESOURCE_CONNECTED = 0x00000001;
        const int RESOURCE_GLOBALNET = 0x00000002;
        const int RESOURCE_REMEMBERED = 0x00000003;

        const int RESOURCETYPE_ANY = 0x00000000;
        const int RESOURCETYPE_DISK = 0x00000001;
        const int RESOURCETYPE_PRINT = 0x00000002;

        const int RESOURCEDISPLAYTYPE_GENERIC = 0x00000000;
        const int RESOURCEDISPLAYTYPE_DOMAIN = 0x00000001;
        const int RESOURCEDISPLAYTYPE_SERVER = 0x00000002;
        const int RESOURCEDISPLAYTYPE_SHARE = 0x00000003;
        const int RESOURCEDISPLAYTYPE_FILE = 0x00000004;
        const int RESOURCEDISPLAYTYPE_GROUP = 0x00000005;

        const int RESOURCEUSAGE_CONNECTABLE = 0x00000001;
        const int RESOURCEUSAGE_CONTAINER = 0x00000002;


        const int CONNECT_INTERACTIVE = 0x00000008;
        const int CONNECT_PROMPT = 0x00000010;
        const int CONNECT_REDIRECT = 0x00000080;
        const int CONNECT_UPDATE_PROFILE = 0x00000001;
        const int CONNECT_COMMANDLINE = 0x00000800;
        const int CONNECT_CMD_SAVECRED = 0x00001000;

        const int CONNECT_LOCALDRIVE = 0x00000100;
        #endregion

        #region Errors
        const int NO_ERROR = 0;

        const int ERROR_ACCESS_DENIED = 5;
        const int ERROR_ALREADY_ASSIGNED = 85;
        const int ERROR_BAD_DEVICE = 1200;
        const int ERROR_BAD_NET_NAME = 67;
        const int ERROR_BAD_PROVIDER = 1204;
        const int ERROR_CANCELLED = 1223;
        const int ERROR_EXTENDED_ERROR = 1208;
        const int ERROR_INVALID_ADDRESS = 487;
        const int ERROR_INVALID_PARAMETER = 87;
        const int ERROR_INVALID_PASSWORD = 1216;
        const int ERROR_MORE_DATA = 234;
        const int ERROR_NO_MORE_ITEMS = 259;
        const int ERROR_NO_NET_OR_BAD_PATH = 1203;
        const int ERROR_NO_NETWORK = 1222;

        const int ERROR_BAD_PROFILE = 1206;
        const int ERROR_CANNOT_OPEN_PROFILE = 1205;
        const int ERROR_DEVICE_IN_USE = 2404;
        const int ERROR_NOT_CONNECTED = 2250;
        const int ERROR_OPEN_FILES  = 2401;

        private struct ErrorClass 
        {
            public int num;
            public string message;
            public ErrorClass(int num, string message) 
            {
                this.num = num;
                this.message = message;
            }
        }


        // Created with excel formula:
        // ="new ErrorClass("&A1&", """&PROPER(SUBSTITUTE(MID(A1,7,LEN(A1)-6), "_", " "))&"""), "
        private static ErrorClass[] ERROR_LIST = new ErrorClass[] {
            new ErrorClass(ERROR_ACCESS_DENIED, "Error: Access Denied"), 
            new ErrorClass(ERROR_ALREADY_ASSIGNED, "Error: Already Assigned"), 
            new ErrorClass(ERROR_BAD_DEVICE, "Error: Bad Device"), 
            new ErrorClass(ERROR_BAD_NET_NAME, "Error: Bad Net Name"), 
            new ErrorClass(ERROR_BAD_PROVIDER, "Error: Bad Provider"), 
            new ErrorClass(ERROR_CANCELLED, "Error: Cancelled"), 
            new ErrorClass(ERROR_EXTENDED_ERROR, "Error: Extended Error"), 
            new ErrorClass(ERROR_INVALID_ADDRESS, "Error: Invalid Address"), 
            new ErrorClass(ERROR_INVALID_PARAMETER, "Error: Invalid Parameter"), 
            new ErrorClass(ERROR_INVALID_PASSWORD, "Error: Invalid Password"), 
            new ErrorClass(ERROR_MORE_DATA, "Error: More Data"), 
            new ErrorClass(ERROR_NO_MORE_ITEMS, "Error: No More Items"), 
            new ErrorClass(ERROR_NO_NET_OR_BAD_PATH, "Error: No Net Or Bad Path"), 
            new ErrorClass(ERROR_NO_NETWORK, "Error: No Network"), 
            new ErrorClass(ERROR_BAD_PROFILE, "Error: Bad Profile"), 
            new ErrorClass(ERROR_CANNOT_OPEN_PROFILE, "Error: Cannot Open Profile"), 
            new ErrorClass(ERROR_DEVICE_IN_USE, "Error: Device In Use"), 
            new ErrorClass(ERROR_EXTENDED_ERROR, "Error: Extended Error"), 
            new ErrorClass(ERROR_NOT_CONNECTED, "Error: Not Connected"), 
            new ErrorClass(ERROR_OPEN_FILES, "Error: Open Files"), 
        };

        private static string getErrorForNumber(int errNum) 
        {
            foreach (ErrorClass er in ERROR_LIST) 
            {
                if (er.num == errNum) return er.message;
            }
            return "Error: Unknown, " + errNum;
        }
        #endregion

        [DllImport("Mpr.dll")] private static extern int WNetUseConnection(
            IntPtr hwndOwner,
            NETRESOURCE lpNetResource,
            string lpPassword,
            string lpUserID,
            int dwFlags,
            string lpAccessName,
            string lpBufferSize,
            string lpResult
        );

        [DllImport("Mpr.dll")] private static extern int WNetCancelConnection2(
            string lpName,
            int dwFlags,
            bool fForce
        );

        [StructLayout(LayoutKind.Sequential)] private class NETRESOURCE
        { 
            public int dwScope = 0;
            public int dwType = 0;
            public int dwDisplayType = 0;
            public int dwUsage = 0;
            public string lpLocalName = "";
            public string lpRemoteName = "";
            public string lpComment = "";
            public string lpProvider = "";
        }


        public static string connectToRemote(string remoteUNC, string username, string password) 
        {
            return connectToRemote(remoteUNC, username, password, false);
        }

        public static string connectToRemote(string remoteUNC, string username, string password, bool promptUser) 
        {
            NETRESOURCE nr = new NETRESOURCE();
            nr.dwType = RESOURCETYPE_DISK;
            nr.lpRemoteName = remoteUNC;
            //          nr.lpLocalName = "F:";

            int ret;
            if (promptUser) 
                ret = WNetUseConnection(IntPtr.Zero, nr, "", "", CONNECT_INTERACTIVE | CONNECT_PROMPT, null, null, null);
            else 
                ret = WNetUseConnection(IntPtr.Zero, nr, password, username, 0, null, null, null);

            if (ret == NO_ERROR) return null;
            return getErrorForNumber(ret);
        }

        public static string disconnectRemote(string remoteUNC) 
        {
            int ret = WNetCancelConnection2(remoteUNC, CONNECT_UPDATE_PROFILE, false);
            if (ret == NO_ERROR) return null;
            return getErrorForNumber(ret);
        }
    }
}

Start debugging, as soon as you've arrived at a breakpoint or used Debug > Break All, use Debug > Windows > Modules. You'll see a list of all the assemblies that are loaded into the process. Locate the one you want to get debug info for. Right-click it and select Symbol Load Information. You'll get a dialog that lists all the directories where it looked for the .pdb file for the assembly. Verify that list against the actual .pdb location. Make sure it doesn't find an old one.

In normal projects, the assembly and its .pdb file should always have been copied by the IDE into the same folder as your .exe, i.e. the bin\Debug folder of your project. Make sure you remove one from the GAC if you've been playing with it.