I think you are attacking it from the wrong angle by trying to encode all posted data.
Note that a "<" could also come from other outside sources, like a database field, a configuration, a file, a feed and so on.
Furthermore, "<" is not inherently dangerous. It's only dangerous in a specific context: when writing strings that haven't been encoded to HTML output (because of XSS).
In other contexts different sub-strings are dangerous, for example, if you write an user-provided URL into a link, the sub-string "javascript:" may be dangerous. The single quote character on the other hand is dangerous when interpolating strings in SQL queries, but perfectly safe if it is a part of a name submitted from a form or read from a database field.
The bottom line is: you can't filter random input for dangerous characters, because any character may be dangerous under the right circumstances. You should encode at the point where some specific characters may become dangerous because they cross into a different sub-language where they have special meaning. When you write a string to HTML, you should encode characters that have special meaning in HTML, using Server.HtmlEncode. If you pass a string to a dynamic SQL statement, you should encode different characters (or better, let the framework do it for you by using prepared statements or the like)..
When you are sure you HTML-encode everywhere you pass strings to HTML, then set ValidateRequest="false" in the <%@ Page ... %> directive in your .aspx file(s).
In .NET 4 you may need to do a little more. Sometimes it's necessary to also add <httpRuntime requestValidationMode="2.0" /> to web.config (reference).
URIs identify and URLs locate; however, locators are also identifiers, so every URL is also a URI, but there are URIs which are not URLs.
Examples
This is my name, which is an identifier.
It is like a URI, but cannot be a URL, as it tells you nothing about my location or how to contact me.
In this case it also happens to identify at least 5 other people in the USA alone.
- 4914 West Bay Street, Nassau, Bahamas
This is a locator, which is an identifier for that physical location.
It is like both a URL and URI (since all URLs are URIs), and also identifies me indirectly as "resident of..".
In this case it uniquely identifies me, but that would change if I get a roommate.
I say "like" because these examples do not follow the required syntax.
Popular confusion
From Wikipedia:
In computing, a Uniform Resource Locator (URL) is a subset of the Uniform Resource Identifier (URI) that specifies where an identified resource is available and the mechanism for retrieving it. In popular usage and in many technical documents and verbal discussions it is often incorrectly used as a synonym for URI, ... [emphasis mine]
Because of this common confusion, many products and documentation incorrectly use one term instead of the other, assign their own distinction, or use them synonymously.
URNs
My name, Roger Pate, could be like a URN (Uniform Resource Name), except those are much more regulated and intended to be unique across both space and time.
Because I currently share this name with other people, it's not globally unique and would not be appropriate as a URN. However, even if no other family used this name, I'm named after my paternal grandfather, so it still wouldn't be unique across time. And even if that wasn't the case, the possibility of naming my descendants after me make this unsuitable as a URN.
URNs are different from URLs in this rigid uniqueness constraint, even though they both share the syntax of URIs.
Best Answer
Routing is not part of ASP.NET MVC - it's just part of ASP.NET itself. The good news is that it works with both MVC and WebForms (ASPX files). Check out Phil Haack's blog post on how to get this to work.
The only changes you need to make to your application are to add some configuration items to web.config and then register your routes in global.asax.cs (or global.asax.vb if you're using VB).