Sql – Is it possible to sync two sql express servers with MS Sync Framework

LINQ to SQL only supports 1 to 1 mapping of database tables, views, sprocs and functions available in Microsoft SQL Server. It's a great API to use for quick data access construction to relatively well designed SQL Server databases. LINQ2SQL was first released with C# 3.0 and .Net Framework 3.5.

LINQ to Entities (ADO.Net Entity Framework) is an ORM (Object Relational Mapper) API which allows for a broad definition of object domain models and their relationships to many different ADO.Net data providers. As such, you can mix and match a number of different database vendors, application servers or protocols to design an aggregated mash-up of objects which are constructed from a variety of tables, sources, services, etc. ADO.Net Framework was released with the .Net Framework 3.5 SP1.

This is a good introductory article on MSDN: Introducing LINQ to Relational Data

Syntax:

ALTER TABLE {TABLENAME} 
ADD {COLUMNNAME} {TYPE} {NULL|NOT NULL} 
CONSTRAINT {CONSTRAINT_NAME} DEFAULT {DEFAULT_VALUE}
WITH VALUES

Example:

ALTER TABLE SomeTable
        ADD SomeCol Bit NULL --Or NOT NULL.
 CONSTRAINT D_SomeTable_SomeCol --When Omitted a Default-Constraint Name is autogenerated.
    DEFAULT (0)--Optional Default-Constraint.
WITH VALUES --Add if Column is Nullable and you want the Default Value for Existing Records.

Notes:

Optional Constraint Name:
If you leave out CONSTRAINT D_SomeTable_SomeCol then SQL Server will autogenerate
    a Default-Contraint with a funny Name like: DF__SomeTa__SomeC__4FB7FEF6

Optional With-Values Statement:
The WITH VALUES is only needed when your Column is Nullable
    and you want the Default Value used for Existing Records.
If your Column is NOT NULL, then it will automatically use the Default Value
    for all Existing Records, whether you specify WITH VALUES or not.

How Inserts work with a Default-Constraint:
If you insert a Record into SomeTable and do not Specify SomeCol's value, then it will Default to 0.
If you insert a Record and Specify SomeCol's value as NULL (and your column allows nulls),
    then the Default-Constraint will not be used and NULL will be inserted as the Value.

Notes were based on everyone's great feedback below.
Special Thanks to:
    @Yatrix, @WalterStabosz, @YahooSerious, and @StackMan for their Comments.