Sql-server – Pad a string with leading zeros so it’s 3 characters long in SQL Server 2008

Syntax:

ALTER TABLE {TABLENAME} 
ADD {COLUMNNAME} {TYPE} {NULL|NOT NULL} 
CONSTRAINT {CONSTRAINT_NAME} DEFAULT {DEFAULT_VALUE}
WITH VALUES

Example:

ALTER TABLE SomeTable
        ADD SomeCol Bit NULL --Or NOT NULL.
 CONSTRAINT D_SomeTable_SomeCol --When Omitted a Default-Constraint Name is autogenerated.
    DEFAULT (0)--Optional Default-Constraint.
WITH VALUES --Add if Column is Nullable and you want the Default Value for Existing Records.

Notes:

Optional Constraint Name:
If you leave out CONSTRAINT D_SomeTable_SomeCol then SQL Server will autogenerate
    a Default-Contraint with a funny Name like: DF__SomeTa__SomeC__4FB7FEF6

Optional With-Values Statement:
The WITH VALUES is only needed when your Column is Nullable
    and you want the Default Value used for Existing Records.
If your Column is NOT NULL, then it will automatically use the Default Value
    for all Existing Records, whether you specify WITH VALUES or not.

How Inserts work with a Default-Constraint:
If you insert a Record into SomeTable and do not Specify SomeCol's value, then it will Default to 0.
If you insert a Record and Specify SomeCol's value as NULL (and your column allows nulls),
    then the Default-Constraint will not be used and NULL will be inserted as the Value.

Notes were based on everyone's great feedback below.
Special Thanks to:
    @Yatrix, @WalterStabosz, @YahooSerious, and @StackMan for their Comments.

If you are on SQL Server 2017 or Azure, see Mathieu Renda answer.

I had a similar issue when I was trying to join two tables with one-to-many relationships. In SQL 2005 I found that XML PATH method can handle the concatenation of the rows very easily.

If there is a table called STUDENTS

SubjectID       StudentName
----------      -------------
1               Mary
1               John
1               Sam
2               Alaina
2               Edward

Result I expected was:

SubjectID       StudentName
----------      -------------
1               Mary, John, Sam
2               Alaina, Edward

I used the following T-SQL:

SELECT Main.SubjectID,
       LEFT(Main.Students,Len(Main.Students)-1) As "Students"
FROM
    (
        SELECT DISTINCT ST2.SubjectID, 
            (
                SELECT ST1.StudentName + ',' AS [text()]
                FROM dbo.Students ST1
                WHERE ST1.SubjectID = ST2.SubjectID
                ORDER BY ST1.SubjectID
                FOR XML PATH ('')
            ) [Students]
        FROM dbo.Students ST2
    ) [Main]

You can do the same thing in a more compact way if you can concat the commas at the beginning and use substring to skip the first one so you don't need to do a sub-query:

SELECT DISTINCT ST2.SubjectID, 
    SUBSTRING(
        (
            SELECT ','+ST1.StudentName  AS [text()]
            FROM dbo.Students ST1
            WHERE ST1.SubjectID = ST2.SubjectID
            ORDER BY ST1.SubjectID
            FOR XML PATH ('')
        ), 2, 1000) [Students]
FROM dbo.Students ST2