Taken from off-topic question at https://stackoverflow.com/questions/8748388/how-to-add-administrators-to-an-app-if-only-developer-role-is-filled by anon user
I am the designated developer for 11 apps however no administrator exists. Some apps need to be deleted and other users added to other roles.
Is there a way to add an admin?
Best Answer
Deleting oneself (the only administrator) from one of the test applications results in
So it's possible that the original administrator deleted their Facebook account or it got suspended. Or your app was victim of this bug: http://bugs.developers.facebook.net/show_bug.cgi?id=18848
You should contact Facebook directly.
Source: https://stackoverflow.com/a/8748796/321505