Now, its showing me some offline friends on the top and making me scroll to see the remaining friends who are actually online!!!
Facebook – How to get Facebook chat to show me online friends on top instead of a random list on top and online friends at the bottom
Related Solutions
I believe that the "Main" section are friends you have put into a specific list. The "More Online Friends" are friends who are not placed into lists.
The lag in online/offline inaccuracy is due to the refresh rate set by Facebook.
Facebook is HUGE. They have a refresh/cache for the online/offline of users. Different areas most likely have different cache/refresh times.
You can find it by pointing your browser to http://www.facebook.com/bookmarks/lists then Restricted or clicking friends on the left on Facebook homepage (you might need to click more).
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Best Answer
There's no option built in Facebook UI till date, so NO, you can't sort your list.
Also, the Facebook API does not allows any such alteration.