Electronic – How to make a component only be on when a capacitor powers it

First draw the circuit with positive power at the top negative at bottom, power currents generally flowing down, and signals feeding left to right. If you do that, two useful things happen. First, many circuits will be drawn similarly most of the time, and you learn to recognize them after a while. Second, you will confuse yourself and anyone you ask to help you less in what is actually going on and what you hooked up where.

Redrawing the schematic so as to better illuminate the circuit, we have:

It is obvious why the LED doesn't come on, or blips on for a short time at best. That is because it is in series with capacitor C1. Capacitors block DC current. There can't be any sustained current thru the LED.

What you probably intended was something like this:

This allows the capacitor to be like a small reservoir for the LED. It will keep the LED lit for a short time after the transistor is shut off.

With this circuit you can see how a little base current can control a larger collector current, which is how a bipolar transistor is used to make circuits with gain.

However, the values don't seem right for what I think you want this circuit to do. Most LEDs are rated for 20 mA maximum, so R2 should be sized to that this can't be exceeded. Let's say it's a green LED and drops 2.1 V at full current, and that the transistor would drop another 200 mV. That leaves 9.0V - 2.1V - 200mV = 6.7V accross R2. From Ohm's law, 6.7V / 20mA = 335Ω, which is the minimum resistance to keep the LED current within spec. Therefore use the next higher common value of 360 Ω. That still results in nearly 19 mA LED current. You won't notice the brightness difference between 19 mA and 20 mA even in a side by side comparison.

Another problem is that there isn't enough base current to reliably light the LED to its full value. Let's say the B-E junction drops 600 mV, then there is 8.4 V accross R1, which results in 84 µA. Let's say you can count on a gain of 50, so the minimum LED current is only 4.2 mA. That's enough to see it light up on your desk, but not to reach full brightness. In reality, you will likely get a gain higher than 50, so you will get more LED current, but relying on that is bad design.

Let's work backwards to see what R1 should be to fully turn on the LED. Again we'll assume the transistor has a gain of 50, and we've already said the maximum LED current is about 20 mA. 20mA / 50 = 400µA. With 8.4 V accross R1 from above and using Ohm's law again, the maximum R1 value is 8.4V / 400µA = 21kΩ, so the common value of 20 kΩ would make this a nice and reliable circuit if the intent is to light the LED to full brightness.

As cowbydan stated, placing the capacitor in series to the LED will block DC currents. To achieve the desired effect of a glowing LED after removing the batteries you need a circuit similar to this :

^{simulate this circuit – Schematic created using CircuitLab}

The capacitor needs to be in parallel to the LED and the polarity of the capacitor needs to match the polarity of the connected battery. The resistor R1 is not mandatory in your particular application but it reduces the current which the LED consumes. A larger resistor value will increase the time the LED glows after you remove the battery but will also decrease its brightness. Just test it with some different values. Choosing a LED with a lower voltage rating would require a resistor in series to it to reduce the voltage.