Electronic – Why is the Anode positive if Anions are negative…

charge

When I was younger I learned in Chemistry class that Anions were negatively charged and Cations were positively charged (Fun fact: I memorized this because anion sounds like onion which makes you cry and is therefore negative; while cation has cat in it and cats are cute, so it's positive 😛).

Now that I've started getting into electronics, I've learned that the Anode is the positive lead while the Cathode is the negative one. It seems odd to me that they're reversed; can someone explain why this is?

Best Answer

From Wiki:

Faraday also introduced the words anion for a negatively charged ion, and cation for a positively charged one. In Faraday's nomenclature, cations were named because they were attracted to the cathode in a galvanic device and anions were named due to their attraction to the anode.

In the diode, and specifically in the so-called depletion region, there is diffusion of carriers (electrons and holes) from one region to the other. Since the Anode is positively doped, it will attract electrons from the cathode, and this will cause the formation of Anions in its side of the depletion region.