Electronic – Why is the transistor ON when charge is only going to the base

Okay, looking at the picture I think you may have the transistor the wrong way round.

Try turning it round.

See this picture for reference:

As you can see the collector is on the right with the flat part facing you, so you have the collector connected to the LED in your circuit (if the 2N2222A part you are using has the same pinout)
I got the picture from here.

EDIT - It's actually a 2N222A, but the above advice still goes as the pinout appears to be the same from the picture posted.

As Russell mentions the more standard way is to connect the LED to the collector, but your circuit should work if set up correctly.

The transistor may act as a switch or a variable resistor. If no voltage is applied to the base (more precisely: no current flowing into the base) then the switch is open. As base current is applied it gets amplified by the transistor into an N times larger collector current. The "N" is an important transistor parameter, called \$H_{FE}\$, and it defines the current amplification factor. For general purpose transistors this is often around 100.

So if you apply a base voltage (you need a series resistor!) so that there will flow, say, 1 mA, then there will be 100 mA collector current if the circuit allows it. That means that other components may limit that current to a lower value. Let's assume your LED has a 2 V voltage drop, that will be rather constant for that type of LED. Then assuming the transistor is fully conducting (no voltage drop between collector and emitter) you'll have 9 V battery voltage - 2 V LED voltage = 7 V across the resistor. If we choose a resistor value of 350 Ω then, according to Ohm's Law we have a current of 7 V/ 350 Ω = 20 mA through that resistor and therefore also through the LED. (20 mA is a typical current for an indicator type of LED.)
So, while the transistor would like to draw 100 mA, the resistor will always limit that to the lower 20 mA.

You don't say what the signal from the amplifier is. Is that a line level (500 mV) or a speaker output level (3 V for 1 W)? In the first case the voltage will be too low; a transistor's base has to be at 0.7 V minimum before current starts to flow. If you use the speaker output you can use a 1 kΩ resistor in series with the output to limit the base current.

Also place a diode (1N4148) in anti-parallel with the base: cathode to the base, anode to ground. This prevents too large negative voltages across the base, which would destroy the transistor.