Electronic – Should series connected battery cells have similar internal resistance and to what degree

batteriesinternal-resistancelithium ionpowertesting

I have some Toshiba SCiB cells that I wish to string in 4s configuration. These are Lithium Titanate (LTO) cells. They have a 20Ah capacity and operate safely between 1.5 V and 2.7 V. The cells were obtained after some light use. I was told they still have good capacity and should still have a solid amount of cycles left.

I have 14 cells and I want to know how to determine which four cells will perform the best when strung together. I could just grab four cells and place them in series ( with appropriate cell managing of course). Would it be worth it to measure the internal resistance of each cell and place in series the four cells with the most similar internal resistance?

Best Answer

It will be almost impossible to match internal resistance since this is defined by the state of charge, temperature etc.
The best way to match the cells is to fully charge to the same endpoint voltage and then discharge each cell with the same load current (a simple load resistor) to a fixed endpoint voltage measured with a decent multimeter. This will give you the approximate capacity of each individual cell.

Select 4 cells with the closest capacity (ie time to your discharge endpoint can be used).

The internal resistance of all four cells you select is effectively in series for discharging, so the impact on the terminal voltage of the 4S under load is impacted by all the internal resistance.

If you match the capacities of the batteries closely, you may not need a BMS. However a BMS is always better.

This may help your understanding of the subject.