In general, it is the states of the PN junctions inside the transistor which will determine what operation region it is in. However, after gathering some experience, one can deduce the states of the above junctions by inspecting the circuit itself without actually measuring the voltages at the terminals.
An example:
Lets analyze the circuit you've referenced.
Once the switch is closed a current of approximately \$1mA\$ will flow into the base, which will cause:
$$V_{BE} \approx 2V$$
Since this is higher than the minimum of \$0.6V-0.7V\$ for being out of cut-off - the transistor is in one of its operational modes. In reality, the Base-to-Emitter voltage will not rise much beyond \$0.6V-0.7V\$ (due to presence of protection resistor R1), which means that the Base current will be a bit higher than \$1mA\$.
Knowing that the motor is \$12V, 100mA\$, and that the transistor is capable of handling \$100mA\$ Collector-to-Emitter current, we can deduce that:
$$I_C = I_{Motor} \approx 100mA$$
Given that we know (from motor's specs) that the motor will consume \$100 mA\$ at \$12V\$, the voltage on the motor:
$$V_{Motor} \approx 12V$$
Which leads to:
$$V_C \approx 0V$$
But this means that Collector-to-Base junction is forward biased which implies that the transistor in saturation.
The above analysis is quite general for this configuration (full voltage rated motor switched by matching BJT), therefore, in majority of circuits like this one, the transistor will be in saturation.
Experienced engineers perform the analysis above at a glance, knowing that the transistor in saturation a second after they see the schematics.
While interesting, your predictions are incorrect.
The cause of your mistake is rooted in the very first paragraph of the question - you misinterpret the meaning of built-in voltage. Allow me to write a step-by-step answer - you may already know most of the theory, but there are others who don't.
Doped Silicon
Without loss of generality let me talk about Silicon.
Doping is a process of adding non-silicon atoms into (otherwise pure) bulk of silicon. The dopants (=atoms which were added) are neutral, therefore the material stays neutral too. However, dopants have very interesting property - each dopant atom contribute one free charge carrier. This charge carriers can be used (and are used) as the main current carriers in semiconductor devices.
"Donor" dopants add negatively charged free carriers - electrons. The resulting material is called \$n\$-type silicon.
"Acceptor" dopants add positively charged free carriers - holes. The resulting material is called \$p\$-type silicon.
Depletion region
When bringing two oppositely doped pieces of Silicon into a contact, the severe difference in free carriers concentrations give rise to diffusion currents (there are much more holes at the \$p\$ side and much more electrons at the \$n\$ side). While free carriers diffuse across the boundary they "leave behind" static dopant ions. The carriers themselves neutralize each-other (recall that they have negative polarities), but the ions stay in their places and give rise to local electric fields:
The diffusion described above continues until the magnitude of the electric field, induced by the "exposed" dopant ions, is just enough to balance the tendency of free carriers to diffuse.
The region containing exposed ions is called Depletion Region. There is an electric field inside this region which prevents from free carriers to diffuse further.
Built-in voltage
Since there is an electric field in depletion region, there is a potential difference associated with this field. This potential difference is called "Built-in voltage" (usually denoted by \$V_{bi}\$; it is this voltage that you call \$V_{eq}\$).
Now is the most confusing fact about built-in voltage: it can't be observed externally. This means that if you take a voltmeter and try to measure the voltage between \$p\$ and \$n\$ sides of the diode when it is in thermal equilibrium (i.e. no external bias) - you'll read 0V.
Wrong interpretation
The first paragraph of your question suggests that you think of built-in voltage as representing the potential difference between the two sides of a diode. This is not the case: the potential difference is 0V in thermal equilibrium, and the built-in voltage only compensates for a diffusion tendency.
However, it is true that when an external bias is applied, the magnitude of the voltage across depletion region is reduced:
$$V_{depletion}=V_{bi}-V_{applied}$$
If \$V_A>0\$ (forward bias): the voltage across depletion region reduces and the width of the region reduces. In this case the diode will conduct a forward-bias current which has exponential dependence on \$V_A\$.
If \$V_A<0\$ (reverse bias): the voltage across depletion region increases and the width of the region increases. The diode will not conduct any appreciable current in reverse bias mode.
Now I suggest you'll try to reconsider your models, taking into account that there is no potential differences between between parts of semiconductors devices in thermal equilibrium.
Best Answer
That appears to be just an extension of the saturation region if CB and BE are both forward biased: http://en.wikipedia.org/wiki/Bipolar_junction_transistor#Regions_of_operation
It looks like your definition of saturation region is overly narrow.
If BE is reverse biased and BC is forward biased, then it still acts like a transistor, but because of the physical way bjt's are setup, you have much less gain than forward active.